| Status | Role | Dates | Source | |
|---|---|---|---|---|
| Sibusiso Obed Nkomonde | - | Member | — | People's Assembly |
| Sifiso Thobani Derrick Buthelezi | - | Member | — | People's Assembly |
| Sigoga Caiphus Mkhwanazi | - | Member | — | People's Assembly |
| Sihlesenkosi Oscar Njongo | - | Member | — | People's Assembly |
| Sikhumbuzo Shepherd Sibisi | - | Member | — | People's Assembly |
| Sibusiso Goodlucky Ngema | - | Member | — | People's Assembly |
| Sibusiso Richard Ntuli | - | Member | — | People's Assembly |
| Sidumo Leo Mbanjwa | - | Member | — | People's Assembly |
| Sifiso Barnabas Mchunu | - | Member | — | People's Assembly |
| Sifundo Mabadi | - | Member | — | People's Assembly |
| Silindile Yenziwe Mbatha | - | Member | — | People's Assembly |
| Simangele Angeline Msomi | - | Member | — | People's Assembly |
| Simingayesonke Wiseman Mcoyi | - | Member | — | People's Assembly |
| Simiso Alfred Ntuli | - | Member | — | People's Assembly |
| Simon Enos Mabaso | - | Member | — | People's Assembly |
| Simosakhe David Mnguni | - | Member | — | People's Assembly |
| Simphiwe Lucky Mzobe | - | Member | — | People's Assembly |
| Sindisiwe Abegail Maphumulo | - | Member | — | People's Assembly |
| Sindisiwe Veronicah Dlamini-Nkambule | - | Member | — | People's Assembly |
| Sindiswa Hester Boyi | - | Member | — | People's Assembly |
| Siphamandla Vincent Mthethwa | - | Member | — | People's Assembly |
| Sipho Johannes Mdakane | - | Member | — | People's Assembly |
| Sipho Sibiya | - | Member | — | People's Assembly |
| Siphumule Ishmael Ntombela | - | Member | — | People's Assembly |
| Skhumbuzo Lovers Mhlanga | - | Member | — | People's Assembly |